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The thermal properties of a novel homoionic ionic liquid [LiN(m)][PF(6)] (1, N(m) = 2, 4-dimethylpyridinium; m = 2, 3) and its mesogenic dications, LiN(m)M(+)[PF(6)] (2; m = 2, 4-methyldipyridinium; 3; m = 3, 3,4,5-tetramethylpyridinium; 4), are compared in order to understand the conformational effect on the liquid-gel transition. A higher degree of conformational freedom is attained in the mesogenic dication 3 compared to the non-mesogenic 2. In 3, the conformational freedom of the cation seems to be supported, as the liquid-gel transition temperature (T(g)) is higher. Conversely, a higher T(g) is observed for 2.More than 40,000 people have signed up for a free NHS tattoo treatment in Germany.
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Why the Germans are investing in Big Pharma: A therapeutic tattoo (left) and a neo-natal one (right)
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Léonard Klein (9 March 1894, Paris – 21 September 1940) was a French painter, engraver and writer.
His father, a lawyer, died when he was five years old, and his mother supported the family by working as a seamstress. When he was fourteen, his head was injured after a fall on a staircase, and he was bedridden for several years. It was at this time that he began painting in his bedroom. He eventually recovered his health and went to the École des Beaux-Arts, where he studied for three years under Pierre Bonnard. After earning a bachelor of arts degree in 1914, he applied to Le Havre Art School and was accepted. His teachers at Le Havre were :